Sabbagh, Haidar; Eu, Byung Chan - In: Physica A: Statistical Mechanics and its Applications 389 (2010) 12, pp. 2325-2338
In this paper, a molecular theory of self-diffusion coefficient is developed for polymeric liquids (melts) on the basis … for the generic van der Waals equation of state, which in turn makes it possible to calculate the self-diffusion … polymer melts of N monomers, the N dependence of the self-diffusion coefficient is N−1 for the small values of N, an exponent …