A systematic solution procedure for the Fokker-Planck equation of a Brownian particle in the high-friction case

The motion of a Brownian particle in an external field can be described on two levels: by a Fokker-Planck equation for the joint probability distribution of position and velocity, and by a Smoluchowski equation for the distribution in position space only. We derive the second description, with corrections, from the first by means of a systematic expansion procedure of the Chapman-Enskog type in terms of the inverse friction coefficient. We also derive equations describing the initial period, when the Smoluchowski description is not yet valid; in particular we find formulae connecting the initial value to be used for the Smoluchowski equation with that of the full Fokker-Planck equation. The special case of an harmonically bound Brownian particle can be solved exactly; the results are used to check and to illustrate our expressions for general potential.