Consideration of initial correlations of the same type in reactions A+B→B and A+B→C+B
A new method is used to derive the binary non-markovian integro-differential kinetic equations of irreversible reactions with respect to initial correlations of the same type. The source of inhomogeneous integro-differential equation is determined by initial correlations which is in full accord with the properties of kinetic equations of non-equilibrium statistical mechanics. A procedure is found to reduce the derived equations into the differential form of the equations of chemical kinetics.
Year of publication: |
2000
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Authors: | Kipriyanov, A.A. ; Doktorov, A.B. |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 286.2000, 1, p. 109-132
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Publisher: |
Elsevier |
Saved in:
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