Density profiles of hard spheres in a cylinder filled with disordered matrix: application of the Born–Green–Yvon equation
Local densities of a hard sphere fluid in a cylindrical pore filled with quenched disordered hard-sphere matrix are calculated using Born–Green–Yvon equation with Fisher–Methfessel approximation. The solution of replica Ornstein–Zernike equation in the Percus–Yevick approximation for a fluid in a homogeneous matrix is used as an input. A comparison of the density profiles with simulation data shows that the theory works satisfactorily for the considered matrix and fluid densities.
Year of publication: |
1999
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Authors: | Duda, Yu ; Patrykiejew, A ; Pizio, O ; Sokołowski, S |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 265.1999, 3, p. 424-431
|
Publisher: |
Elsevier |
Subject: | Inhomogeneous quenched–annealed fluids | Adsorption | Porosity | Born–Green–Yvon equation |
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