Non-Markovian kinetic equations of dissociation and reversible reaction A+B⇄C in solutions

A consistent many-particle approach has been used to derive integro-differential kinetic equations of a bulk reaction of dissociation in spatially non-uniform solutions in a hydrodynamic approximation with a realistic description of reactants structure and translational mobility. The detailed analysis of the memory function structure of this equation has been carried out, and a microscopic detailed balancing principle of the theory of migration accelerated reactions has been formulated. This has made it possible to formulate a macroscopic kinetic detailed balancing principle for non-Markovian dissociation and recombination kinetics. The non-Markovian kinetic equation of the reversible reaction A+B⇄C in spatially non-uniform systems is proposed. Thermodynamic detailed balancing principle is established.