Simultaneous statistical description of a crystal and fluid
In previous publications by the author the crystalline state was studied with the help of statistical methods based upon utilization of distribution functions. The approximation used for a crystal was not, however, fully adequate for fluids, which did not permit one, in particular, to construct a phase diagram with a triple and critical point. The present paper begins with analysis of the pair correlation function in crystals in order to find an approximation adequate for a crystal as well as fluid. The relevant thermodynamics is developed. It is shown that the fluid can be described, for example, by the hypernetted-chain equation or by the van der Waals or Dieterici equations of state, and such a description will be compatible with the proposed description of the crystal. A phase diagram is constructed which exhibits the region of the crystalline state together with the triple and critical points.
Year of publication: |
2007
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Authors: | Golovko, V.A. |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 374.2007, 1, p. 15-32
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Publisher: |
Elsevier |
Subject: | Statistical thermodynamics of solids | Statistical thermodynamics of liquids | Liquid–solid phase transitions |
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