The irreversible reaction of a geminate pair A+B→Product in dilute solution of scavengers is considered. The scavengers react with one of the partners, say B, thus accelerating its decay and decreasing a geminate reaction yield. The solution of the problem involves certain difficulties due to...

The non-Markovian kinetic equations for local concentrations have been derived in the effective pairs approximation on the basis of the hierarchy for correlation patterns of the reversible reaction A+B⇌C. The equations are shown to agree with the kinetic and thermodynamic detailed balancing...

The non-Markovian binary kinetic equations for a rather realistic model of association–dissociation reaction A+B⇄C in liquid solutions are derived using a newly developed method based on a many-particle consideration. The method leads to an infinite hierarchy for correlation patterns that...

Based on the non-Markovian kinetic equations of the reversible reaction A+B⇄C derived earlier, we have obtained the non-Markovian kinetic equations describing the reaction under consideration on macroscopic space–time scales. They define the non-Markovian kinetics of the systems with...