Hydrogen production based in the corrosion of light metals in water solutions is an interesting alternative. Among all of them, Mg is probably the most adequate metal for energetic purposes due to its high electron density and oxidation potential. A safe and environmental-friendly method of...

This study reports the development of a new system of IL (ionic liquid) with metal complex, chemically crosslinked, electrospun nanofibers based on PVDF (poly(vinylidene fluoride)) as a polymer matrix. The nanofibers were fabricated with different amounts of ionic liquid, PEG (polyethylene...

High purity hydrogen produced by hydrolysis of sodium borohydride can be used directly in (proton exchange membrane) PEM fuel cells for portable devices and automotive applications. The advantages of high storage capacity, quickly start, controllable reaction and mild condition, hydrogen...

Ferromagnetic elements Fe, Ni and Co were immobilized on the porous SiO2 to catalyze the hydrogen generation from aqueous alkaline NaBH4 (sodium borohydride). The porous SiO2 was prepared by silica-surfactant self-assembly and the ferromagnetic catalyst was prepared by chemical reduction. The...

In this study, a new novel bench-scale (5 L) tubular photocatalytic reactor was developed and its feasibility studies were conducted for optimizing the operating variables, namely concentration of sulfide ion, concentration of sulfite ion, pH, catalyst concentration, lamp power, volume of...

This paper presents the exergoeconomic analysis of a novel process generating electric energy and hydrogen. Coal and high-temperature heat are used as input energy to the process. The process is a true “zero-emission process” because (a) no NOX is formed during coal combustion with sulfuric...

OL (Oleic acid)–Cobalt–Lanthanum–Zirconium–Boron nanoparticle was synthesized by chemical reduction of chloride salts of metals in the presence of oleic acid as stabilizing agent. The obtained materials were characterized by XRD (X-ray diffraction), TEM (Transmission electron...

A new hydrogen generation material, Al–Ca alloy, is prepared by ball milling method. Results show the prepared Al–Ca alloy can react with to produce hydrogen, but its hydrogen yield is lower. NaCl addition can further greatly improve hydrogen generation of Al–Ca alloys. The amount of NaCl...

Because of its use in on-board hydrogen portable hydrogen-air fuel cell, hydrogen generation based on the reaction between aluminum and water was evaluated. In the present work, the effect of CoCl2 and NiCl2 on aluminum–water reaction was studied. The amount of hydrogen generated linearly...