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A rigorous reformulation of the Hamiltonian describing a dense exciton system is given in terms of ideal Bose operators. The kinematic implications of the Pauli exclusion principle are treated consistently. It is shown that as a consequence of the fermionic nature of the elementary constituents...
Persistent link: https://www.econbiz.de/10010873124
A quantum-statistical theory of chemical kinetics is presented which takes into account the non-ideality of composite particles (bound states). For the time evolution of the chemical composition operators ϱ(a∣t) a generalized Waldmann-Snider equation is obtained. The general treatment is...
Persistent link: https://www.econbiz.de/10011062613
A statistical theory of chemical kinetics is presented based on the quantum logical concept of chemical observables. The apparatus of Boolean algebra B is applied for the construction of appropriate composition polynomials referring to any stipulated arrangement of the atomic constituents. A...
Persistent link: https://www.econbiz.de/10011063238