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The density profiles of an associating fluid near the (100) plane of the fcc crystalline surface are studied by using a singlet level theory of inhomogeneous associating fluids. The model for the bulk fluid is the one-component hard sphere fluid with an embedded sticky attractive site inside the...
Persistent link: https://www.econbiz.de/10011057503
A two-component model of hard spheres with a spherically symmetric associative interaction between the particles of different species near a hard wall is studied by suing the integral equation method. It is shown that the extended mean spherical approximation for the bulk associating fluid in...
Persistent link: https://www.econbiz.de/10011062597
We consider the application of the integral equation theory to the study of associative fluids in disordered porous networks. The theory also takes into account associative fluid-network interactions. The calculations reported here illustrate the effect of associative forces on the fluid-fluid...
Persistent link: https://www.econbiz.de/10011062776
There has recently been extensive interest in the nature of the melting/freezing transition for a two-dimensional system of molecules interacting with Lennard-Jones 6:12 potentials, which is a prototype for physisorbed systems. We have therefore made a detailed study of the thermodynamics of the...
Persistent link: https://www.econbiz.de/10010585028
The effective interaction between colloidal particles in a solvent of hard spheres, which can polymerize with the formation of chains and rings, is studied. Polymerization results in changes of the effective interaction between the colloid particles, compared with the effective interaction for...
Persistent link: https://www.econbiz.de/10010586347