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The effects of spatial heterogeneities on the slow dynamics of density fluctuations are discussed both in an equilibrium colloidal suspension and in a slightly nonequilibrium colloidal suspension. The long-lived, heterogeneous glassy domains appear near the glass transition and influence the...
Persistent link: https://www.econbiz.de/10011062605
The importance of the dynamic anomaly of the self-diffusion coefficient, which becomes zero at the colloidal glass transition volume fraction φg as DS∼(1−Φ(x,t)/φg)2, has recently been emphasized for understanding structural slowing down in concentrated hard-sphere colloidal suspensions,...
Persistent link: https://www.econbiz.de/10011060085
A simple theory for nonequilibrium density fluctuations in concentrated hard-sphere suspensions of interacting Brownian particles with both hydrodynamic and direct interactions is proposed. The correlation effects due to the many-body hydrodynamic interactions among particles are shown to cause...
Persistent link: https://www.econbiz.de/10010587152
A formal theory of finding a nonlinear stochastic diffusion equation for density fluctuations in a suspension of colloidal hard spheres, which enables us to study the influence of solvent-mediated hydrodynamic interactions between particles as well as the direct interactions, is presented with...
Persistent link: https://www.econbiz.de/10010589138