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This paper is concerned with generalizations of the known local Lagrange formalism of first order. It will be applied to kinetic equations like the Fokker-Planck equation and the Boltzmann equation. In the latter case nonlocal methods are necessary from the very beginning. Nevertheless, in the...
Persistent link: https://www.econbiz.de/10010872818
This study introduces the constrained forms of the Shannon information entropy and Kullback–Leibler cross-entropy functions. Applicable to a closed system, these functions incorporate the constraints on the system in a generic fashion, irrespective of the form or even the number of the...
Persistent link: https://www.econbiz.de/10011057952
We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann–Gibbs standard thermostatistics while, in the latter, Tsallis thermostatistics is...
Persistent link: https://www.econbiz.de/10011062235
Predicting measurable thermodynamic and kinetic properties of solids from first-principles requires the use of statistical mechanics. A major challenge for materials of technological importance arises from the fact that first-principles electronic structure calculations of elementary excited...
Persistent link: https://www.econbiz.de/10010749885
With the help of a general expression of the entropies in extensive and nonextensive systems, some important relations between thermodynamics and statistical mechanics are revealed through the views of thermodynamics and statistical physics. These relations are proved through the MaxEnt approach...
Persistent link: https://www.econbiz.de/10010590048