Computer simulation study of phase separation in a binary mixture with a glass-forming component

We present a computer simulation study of spinodal decomposition with one of the two phases freezing in a glassy state during phase separation. As a model we used the Cahn-Hilliard equation with a concentration-dependent mobility coefficient which decreases rapidly with increasing concentration of the glass-forming component. We solved the Cahn-Hilliard equation numerically for two dimensions. The domain growth depends crucially on the volume fraction of the glassy phase. For high volume fractions, when the glassy phase forms a percolating matrix, a novel coarsening mechanism is discovered, which arises from the migration and coalescence of liquid droplets within the glassy matrix. Various quantities characterizing the time-dependent domain pattern, like droplet size distribution, one- and two-point distribution function and structure factor of the concentration field, are computed. We checked the validity of the dynamic scaling hypothesis.