Non-typical Wulff shapes in a corner: A microscopic derivation
A complete microscopic analysis of the equilibrium shape of a droplet in a corner between two walls is given within a Gaussian SOS model. We derive a statistical mechanical proof of the Winterbottom and the Summertop constructions for the equilibrium shapes, including a proof of generalized Young relations for inclined walls. We discuss a phase diagram with convexity-concavity transitions and wetting transitions induced by changing the inclination of the walls. A possible degeneracy of the solutions of the thermodynamic variational problem at the convexity-concavity transition point is discussed in the Gaussian model from a statistical mechanical point of view.
Year of publication: |
1993
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Authors: | De Coninck, J. ; Fruttero, J. ; Ziermann, A. |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 196.1993, 3, p. 320-334
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Publisher: |
Elsevier |
Saved in:
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