Shear flow effects on a critical binary mixture during phase separation
The effects of a shear flow on growth during phase separation of liquids are investigated. A light scattering study is performed during the spinodal decomposition of a critical binary mixture (water-isobutyric acid) under a Couette flow. Three orthogonal planes are studied in the Fourier space. We find that even a very weak shear can markedly affect the separation process, producing both an anisotropic growth and an unexpected loss of correlation between domains in only one direction. The comparison with a numerical simulation where only the deformation is taken into account enables the flow effects to be separated from growth. In the stretching direction, a scaled function of growth that depends on temperature, time and shear rate is proposed. It is seen to fit the data well.
Year of publication: |
1991
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Authors: | Baumberger, T. ; Perrot, F. ; Beysens, D. |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 174.1991, 1, p. 31-46
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Publisher: |
Elsevier |
Saved in:
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